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Beilstein J. Org. Chem. 2013, 9, 246–253, doi:10.3762/bjoc.9.29
Graphical Abstract
Scheme 1: Hydroarylation of alkynes.
Figure 1: Gold(I) and gold(III) NHC complexes employed as catalysts in this study.
Scheme 2: Hydroarylation of ethyl propiolate with pentamethylbenzene.
Figure 2: Yield in 3{1,1} versus time diagram for the reaction of pentamethylbenzene and ethyl propiolate cat...
Scheme 3: Hydroarylation experiment with catalyst VI under neutral conditions.
Scheme 4: Intramolecular cyclisation through hydroarylation investigated in this work.